Nutrients refers those elements required by plants to grow and survive. Macro nutrients are ones that are needed in larger quantities, called major elements, such as nitrogen (N), phosphorus (P), and potassium. These three are grouped together as NPK. Micro nutrients are ones required in smaller quantities, called trace elements and includes iron (F), boron (B), manganese (Mn), magnesium (Mg) and molybdenum (Mo). Each one has an important role to play in the growth of plants.
There are a number of variants which will determine the availability of these nutrients. The two major factors involved are the pH of the soil and the ability of the soil to hold nutrients which is called its cation exchange capacity (CEC).
The pH levels in the soil have a direct effect on the availability of nutrients to plants.
The technical stuff
pH measures the concentration of hydrogen ions. This has a direct correlation to cation exchange (see below) in the soil. Hydrogen ions are positively charged and will attach to the negative sites (colloids) in the soil particles.
Elements also bind to the soil in varying degrees at different pH levels.
Soil microbiology is greater around the neutral (pH 7) level.
The pH of a soil will tell us if the soil is acidic (pH lower than 7) or alkaline (pH higher than 7). Different ranges of pH affect the availability of nutrients. Each pH level is 10 times that of the previous one e.g. pH 6 is ten times more acidic than pH 7 and pH 5 is one hundred times more acidic than pH 7. A seemingly small pH difference of 0.5 can therefore have a large impact on the growth of plants, depending on what you’re trying to grow.
Most nutrients are available to plants in the range pH 5-7.5. Outside of this some nutrients become ‘locked up’ and are unable to be taken up by the plant. If you suspect that one of your crops has a nutrient deficiency, it may be that the pH is out and adding more nutrients will not solve the problem.
Each crop will experience optimum growth in a certain pH range. Blueberries grow best at around pH 5, potatoes at around pH 6, and beetroot at around pH 7. A detailed list of pH preferences can be found in the pH Requirements of Crops entry in the planting guide category.
The good news is that under organic growing conditions the availability of nutrients covers a greater pH range than with conventional growing practices.
Deficiency vs toxicity
A deficiency is when plants are not getting as much of a nutrient or mineral as they need, and toxicity is when the concentration is too high and they are effectively getting too much of a good thing.
Nutrient deficiency or toxicity is very difficult to diagnose by non-experts as the symptoms, such as discolouration of plant leaves, are not always caused by nutrient imbalances. Also different nutrient deficiencies show as subtle variations in the way the leaves yellow. Yellowing of the leaves could be caused by a nitrogen deficiency, a sulphur deficiency, too much water or not enough. Purple colouring of the leaves can be caused by a phosphorus deficiency or the accumulation of certain carbohydrates.
A high concentration of a particular mineral may result in deficiencies of other essential minerals.
In this instance there may already enough of a nutrient in the soil but it is unable to be taken up by the plant. Adding more will not help
The only sure way of knowing is to have a soil test done.
If the leaves are yellowing or the plant looks sick, check the pH first before adding nutrients. Small test kits are available from gardening supply retailers.
Ensuring that your soil is healthy with good compost and fertilizers and healthy seedlings is a good start. Your plants will soon tell you if there is a problem.
The chart shows the availability of each nutrient element at the various pH levels. The widest parts of the bands are where there is the maximum nutrient availability.
NB: The range at which the nutrients are most available is 6.5 to 7.5 which is slightly alkaline, neutral and slightly acidic.
Phosphorus reacts with other elements at pH levels that are higher (alkaline, over 8.0) and lower (acidic, below 5.0) in a way that makes it less available to plants.
It’s also important that the soil be able to hold on to and store nutrients. Even if nutrients are present in an available form, the soil will not be productive for long if these nutrients leach out of it quickly. In organic gardening we measure how well the soil can hold nutrients by its “cation exchange capacity”. Cations are the ions of elements such as calcium, magnesium, potassium, sodium, and aluminium that have a positive charge.
The particles of clay and humus that hold the cations are negatively charged and are called colloids. The particles are thin and flat with a large surface area for the cations to attach to. The cations (positively charged) are attracted to, and held by the colloids (negatively charged). They are, in effect, a “warehouse” for many of the minerals and nutrients required by our plants. As plants take up nutrients from the colloids more nutrients replace them. When we speak of soils that are “colloidal”, we’re saying that they have a high cation exchange capacity and should remain productive over time if we look after them.
There are a number of factors that influence how well and which particular nutrients are held by the colloids. It is important to keep in mind that a high concentration of a particular nutrient will effectively “saturate” the colloids and make it difficult for the less concentrated cations to bond and be held by the colloids.
The pH of soil also has a complex influence on its ability to hold on to nutrients. An acidic soil (low pH) favours metal cations such as iron, aluminium and copper. Conversely, the high pH range favours the carbonates such as boron, phosphorus and molybdenum. The negative charge on colloids increases with pH, providing maximum availability at around pH 7-7.5, but extremes at either end of the pH range can be detrimental; for example, at very high pH values carbonate cations will reach toxic levels and prevent other major and trace elements from being held by the colloids.
Fortunately a healthy soil with a good level of organic matter will look after all this for us. If you get your soil professionally tested and are told it has a low cation exchange capacity, it can always be improved by adding organic matter.
Humus, the end product of decomposition, has the highest capacity for holding nutrients.
Worm castings are also extremely colloidal, more than clay.
Clay has a very high capacity for holding nutrients, although this does vary with the different types of clay.
See the information in the Product inputs entry in the Soils section for additional ways of increasing organic matter in the soil.
What does it do?
Boron deficiency
Results in:
Causes of boron deficiency
To correct
Toxicity
Boron reaching toxic levels is generally not common in natural circumstances as it tends to leach out of the soil easily.
If it were a problem it would cause tips of older leaves to yellow then fall off.
As it is only required at a very low level, toxicity could occur when it is being intentionally added to the soil
Application:
Commercial products will state application rates and methods.
Comment:
For a quick fix, borax can be used to add boron to soil.
We would apply borax if our soil test indicated that boron was required or if we saw symptoms of a deficiency in our plants. Mix 1 tablespoon in 12 litres of water, dissolving the borax in a little hot water first. You do need to be careful because it is very easy to overdo it and reach a toxic level.
Plants requiring higher levels of boron are apples, cabbage family, strawberries, celery, lettuce, spinach, beetroot, turnips, and sunflowers.
Boron is more likely to be deficient in soils formed from granite or sandstone as opposed to those soils developed from basalt or alluvial origins or those with a high content of clay.
What does it do?
Calcium forces fine clay particles to hold together in larger groups, resulting in larger peds (permanent aggregates of soil) with more space between them which increases aeration, allows water in and good drainage out, creates more room for roots within the soil.
Deficiency
Causes of calcium deficiency
To correct
Add calcium in one of the following forms:
Agricultural Lime (most commonly used)- contains 35% to 38% calcium with very little magnesium
- raises the soil pH (i.e. makes it more alkaline)
- not desirable to use it around plants that like an acidic soil
Gypsum (calcium sulfate) -contains calcium and sulphur -is pH neutral so it won't change the soil pH -it is more soluble than other limes -will add sulphur
Limestone (pure calcium carbonate)- contains 40% calcium and no magnesium
- raises the soil pH (i.e. makes it more alkaline)
- finely ground calcite limestone acts as a slow release form
Dolomite (calcium magnesium carbonate)- contains 12% to 20% calcium and 8% to 11% magnesium
- raises the soil pH (i.e. makes it more alkaline)
- is an untreated limestone rock that also contains magnesium
Soft rock phosphate - calcium and phosphorus
- very slow to break down
- needs to be dug into the soil to help it dissolve
Eggshells - use as a ‘home grown’ additive
- very slow releasing
- need to grind up finely and dig into soil
Oyster shell - Crushed shells are usually oyster and other shellfish and although they are almost totally calcium carbonate they are very hard and coarse to be effective.
Calcium toxicity
Application
Comments
Adding lime and/ or eggshells to compost is a good way to increase soil calcium
The lime needs to be fine (in powder form) to react quickly with the soil.
What does it do?
Deficiency results in:
Causes of copper deficiency
To correct
Copper toxicity
Application
What does it do?
Deficiency
Causes of iron deficiency
To correct
Iron toxicity
Comments
What does it do?
Deficiency
Causes of magnesium deficiency
To correct
Magnesium toxicity
What does it do?
Manganese deficiency
Causes of manganese deficiency
To correct
Toxicity
Comments
What does it do?
Molybdenum deficiency
Causes of molybdenum deficiency
To correct
Toxicity
Comments
What does it do?
Nitrogen deficiency
Causes of nitrogen deficiency
To correct
Iron toxicity
Comments
What does it do?
Phosphorus deficiency
Causes of phosphorus deficiency
To correct
Phosphorus toxicity
Comments
Peas particularly require phosphorus.
What does it do?
Potassium deficiency
Causes of potassium deficiency
To correct
Potassium toxicity
I think that silicon is a bit underrated, as very few gardeners ever talk about it, but as you can see, it has many fine attributes.
What does it do?
Silicon deficiency
Comments
What does it do?
Sulphur deficiency
Causes of sulphur deficiency
To correct
Sulphur toxicity
Comments
What does it do?
Zinc deficiency
Causes of zinc deficiency
To correct
Zinc toxicity